An early challenge to the duopoly of Barcelona and Real Madrid on the goalkeeping front, with Caballero and Palop the early leaders after both recorded clean sheets this weekend. Can they hold off Valdés and Casillas though, both of whom also didn't let in any goals, and probably more importantly, can they resist against the two men brought in to replace them, Kameni and Diego López? They weren't the only ones to keep clean sheets though on another low scoring weekend, and they were joined by Casto (Betis), Aouate (Mallorca) and Raúl Fernández (Athletic), who stood in for the injured Gorka Iraizoz. (25.09.12)
| Zamoras | Games played | Goals against | Difference |
| Caballero (Málaga) | 5 | 2 | -3 |
| Palop (Sevilla) | 4 | 1 | -3 |
| Valdés (Barcelona) | 5 | 3 | -2 |
| Aouate (Mallorca) | 5 | 3 | -2 |
| Casillas (Real Madrid) | 5 | 4 | -1 |
| Rubén (Rayo) | 4 | 3 | -1 |
| Jaime (Valladolid) | 5 | 5 | 0 |
| Javi Varas (Celta) | 5 | 6 | +1 |
| Roberto (Zaragoza) | 5 | 6 | +1 |
| Courtois (Atlético) | 4 | 5 | +1 |
| Aranzubia (Deportivo) | 5 | 7 | +2 |
| Toño (Granada) | 5 | 8 | +3 |
| Diego Alves (Valencia) | 5 | 8 | +3 |
| Munúa (Levante) | 5 | 9 | +4 |
| Bravo (Real Sociedad) | 5 | 9 | +4 |