Week 6: Red cards: Manu García (Alavés), Morata (Atlético Madrid) – two bookings.
Week 7: Red cards: Calero (Espanyol) – straight red; Lenglet (Barcelona), Hernani (Levante) – two bookings. One match ban for 5 yellow cards: Wakaso (Alavés).
Week 8: Red cards: Araújo and Dembélé (Barcelona) – straight reds; Escalante (Eibar), Llorente (Real Sociedad) – two yellow cards. One match ban for 5 yellow cards: Piqué (Barcelona), Germán (Granada).
Two match ban for Dembélé for insulting referee, one match ban for all the others. (08.10.19)
(* suspension pending disciplinary meeting decision)
| Villains | Yellow cards | Red cards (straight) | Games banned | Total points |
| Naldo (Espanyol) | 5 | 1 | 1 | 7 |
| Carvalho (Betis) | 3 | 1 (1) | 1 | 6 |
| Manu García (Alavés) | 4 | 1 | 1 | 6 |
| Wakaso (Alavés) | 5 | 0 | 1 | 6 |
| Pique (Barcelona) | 5 | 0 | 1* | 6 |
| Germán (Granada) | 5 | 0 | 1* | 6 |
| Dembélé (Barcelona) | 1 | 1 (1) | 2* | 5 |
| Morata (Atlético) | 3 | 1 | 1 | 5 |
| Lenglet (Barcelona) | 3 | 1 | 1 | 5 |
| Loren (Betis) | 1 | 1 (1) | 1 | 4 |
| Calero (Espanyol) | 1 | 1 (1) | 1 | 4 |
| Molina (Getafe) | 1 | 1 (1) | 1 | 4 |
| Oscar (Leganés) | 1 | 1 (1) | 1 | 4 |
| Lodi (Atlético) | 2 | 1 | 1 | 4 |
| Escalante (Eibar) | 2 | 1 | 1* | 4 |
| Hernani (Levant) | 2 | 1 | 1 | 4 |
| Llorente (Real Sociedad) | 2 | 1 | 1* | 4 |
| Bale (Real Madrid) | 2 | 1 | 1 | 4 |
| Coquelín (Valencia) | 2 | 1 | 1 | 4 |