Week 9: Red cards: Kangin Lee (Valencia) – straight red; Fran Mérida (Osasuna), Odriozola (Real Madrid) – two bookings.
Week 10: Red cards: Rodrigo (Valencia) – straight reds; Pape Cheikh (Celta) – two yellow cards. One match ban for 5 yellow cards: Yangel (Granada), Cheryshev (Valencia). (28.10.19)
(* suspension pending disciplinary meeting decision)
| Villains | Yellow cards | Red cards (straight) | Games banned | Total points |
| Naldo (Espanyol) | 6 | 1 | 1 | 8 |
| Manu García (Alavés) | 5 | 1 | 1 | 7 |
| Wakaso (Alavés) | 6 | 0 | 1 | 7 |
| Carvalho (Betis) | 3 | 1 (1) | 1 | 6 |
| Pape Cheikh (Celta) | 4 | 1 | 1* | 6 |
| Fran Mérida (Osasuna) | 4 | 1 | 1 | 6 |
| Pique (Barcelona) | 5 | 0 | 1 | 6 |
| Germán (Granada) | 5 | 0 | 1 | 6 |
| Yangel (Granada) | 5 | 0 | 1* | 6 |
| Cheryshev (Valencia) | 5 | 0 | 1* | 6 |
| Dembélé (Barcelona) | 1 | 1 (1) | 2 | 5 |
| Rodrigo (Valencia) | 2 | 1 (1) | 1* | 5 |
| Morata (Atlético) | 3 | 1 | 1 | 5 |
| Lenglet (Barcelona) | 3 | 1 | 1 | 5 |
| Odriozola (Real Madrid) | 3 | 1 | 1 | 5 |
| Loren (Betis) | 1 | 1 (1) | 1 | 4 |
| Jorge Sáenz (Celta) | 1 | 1 (1) | 1 | 4 |
| Calero (Espanyol) | 1 | 1 (1) | 1 | 4 |
| Molina (Getafe) | 1 | 1 (1) | 1 | 4 |
| Oscar (Leganés) | 1 | 1 (1) | 1 | 4 |
| Kang-In Lee (Valencia) | 1 | 1 (1) | 1 | 4 |
| Lodi (Atlético) | 2 | 1 | 1 | 4 |
| Escalante (Eibar) | 2 | 1 | 1 | 4 |
| Hernani (Levant) | 2 | 1 | 1 | 4 |
| Llorente (Real Sociedad) | 2 | 1 | 1 | 4 |
| Bale (Real Madrid) | 2 | 1 | 1 | 4 |
| Coquelín (Valencia) | 2 | 1 | 1 | 4 |