| 14 Sep | Bursaspor |
0-4 | Valencia Tino Costa, Aduríz, Pablo Hernández, Soldado |
Day 1 |
| 14 Sep | Barcelona Messi (2), David Villa, Pedro, Dani Alves |
5-1 | Panathinaikos Govou |
Day 1 |
| 15 Sep | Real Madrid Anita (OG), Higuaín |
2-0 | Ajax |
Day 1 |
| 28 Sep | Auxerre |
0-1 | Real Madrid Di María |
Day 2 |
| 29 Sep | Valencia |
0-1 | Man Utd Hernández |
Day 2 |
| 29 Sep | Rubin Kazan Noboa (Pen) |
1-1 | Barcelona Villa (Pen) |
Day 2 |
| 19 Oct | Real Madrid Cristiano Ronaldo, Özil |
2-0 | AC Milan |
Day 3 |
| 20 Oct | Rangers Edu |
1-1 | Valencia Edu (OG) |
Day 3 |
| 20 Oct | Barcelona Messi (2) |
2-0 | Copenhagen |
Day 3 |
| 2 Nov | Valencia Soldado (2), Tino Costa |
3-0 | Rangers |
Day 4 |
| 2 Nov | Copenhagen Claudemir |
1-1 | Barcelona Messi |
Day 4 |
| 3 Nov | AC Milan Inzaghi (2) |
2-2 | Real Madrid Higuaín, Pedro León |
Day 4 |
| 23 Nov | Ajax |
0-4 | Real Madrid Benzema, Arbeloa, Cristiano Ronaldo (2, 1 Pen) |
Day 5 |
| 24 Nov | Valencia Mata (Pen), Soldado (2), Aduríz, Joaquín, Chori Domínguez |
6-1 | Bursaspor Batalla |
Day 5 |
| 24 Nov | Panathinaikos |
0-3 | Barcelona Pedro (2), Messi |
Day 5 |
| 7 Dec | Man Utd Anderson |
1-1 | Valencia Pablo Hernández |
Day 6 |
| 7 Dec | Barcelona Fontàs, Víctor Vázquez |
2-0 | Rubin Kazan |
Day 6 |
| 8 Dec | Real Madrid Benzema (3), Ronaldo |
4-0 | Auxerre |
Day 6 |